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2013 Vol.50, Issue 2 Preview Page

Technical Report

30 April 2013. pp. 278-296
Abstract
Wax has been serious problem of flow assurance in low temperature environment such as subsea petroleum production system. In reservoir condition, wax is liquid phase, however, it can be crystallized at the temperature under wax appearance temperature. Wax crystal tends to be agglomerated and deposited containing oil, which becomes wax deposits. Wax deposition mechanisms in subsea petroleum production system are molecular diffusion, shear stripping reduction, aging, particle diffusion & inertia effect, shear dispersion, brownian diffusion and gravity settling. Commonly, temperature gradient between internal wall and center flow is major influential factor on wax deposition among oil composition, pressure, flow rate and roughness of flow line wall. To mitigate wax deposition in the subsea production system, thermal management, wax inhibitor and pigging have been widely applied. These technologies and applications at King field, Gannet D field and Cottonwood field are investigated in this study.
해저와 같은 저온환경에서 석유생산 시 빈번히 집적되는 왁스는 저류층에서 석유에 용해되어 있으나 석유의 온도가 왁스생성온도 이하가 되면 결정으로 석출된다. 왁스결정은 서로 결합하면서 오일 등을 함유한 왁스고형물이 되고 석유생산 환경에 따라 분자확산, 전단응력효과, 왁스경화, 확산관성효과, 전단확산, 브라운확산, 중력침전으로 유동관 내벽에서부터 집적된다. 온도, 석유성분, 압력, 유량, 유동관 내벽 거칠기가 왁스집적에 영향을 미칠 수 있으나 일반적으로 유동관 내벽의 온도와 유동단면적 중앙의 온도구배가 왁스집적에 가장 큰 영향을 미친다. 석유의 온도감소율이 커서 왁스집적속도가 가장 빠른 유동관에서의 주요 왁스집적 제어기술은 유동관을 단열 또는 석유를 가열하여 왁스생성온도 이상으로 유지시키는 열제어법, 왁스결정의 성장을 막거나 용해시키는 왁스억제제 주입법, 유동관에 집적된 왁스를 긁어 제거하는 피깅이 있고 이들을 멕시코 만에 위치한 King 유전, Gannet D 유전과 북해에 위치한 Cottonwood 유전의 해저 석유생산시스템에 적용한 사례를 조사하였다.
References
  1. Akbarzadeh, K. and Zougari, M., 2008, “Introduction to a Novel Approach for Modeling Wax Deposition in Fluid Flow. 1. Taylor-Coutte System,” Industrial & Engineering Chemistry Research, Vol. 47, No. 3, pp. 953-963.
  2. Allen, O.T. and Roberts, P.A., 1982, Production Operations : Volume 2, Oil & Gas Consultants International Inc., Tulsa, U.S.A., p. 16.
  3. Azevedo, L.F.A. and Teixeira, A.M., 2003, “A Critical Review of the Modeling of Wax Deposition Mechanisms,” Petroleum Science and Technology, Vol. 3, No. 21, pp. 393-408.
  4. Bacon, M.M. and Romero-Zerŏn, L.B., 2011, “Optimizing Paraffin and Naphthene Wax-Treatment Options Using Cross-Polarized Microscopy,” paper 140838 prepared for presentation at SPE International Symposium on Oilfield Chemistry held in The Woodlands, U.S.A., Apr. 11-13.
  5. Bagatin, R., Busto, C., Correa, S., Margarone, M. and Carniani, C., 2008, “Wax Modeling : There is Need for Alternatives,” paper 115184 presented at SPE Russian Oil & Gas Technology Conference and Exhibition held in Moscow, Russia, Oct. 28-30.
  6. Becker, J.R., 2000, “Oilfield Paraffin Treatments : Hot Oil and Hot Water Compared to Crystal Modifiers,” paper 63123 presented at SPE Annual Technical Conference and Exhibition held in Dallas, U.S.A., Oct. 1-4.
  7. Bern, P.A., Withers, V.R. and Cairns, R.J.R., 1980, “Wax Deposition in Crude Oil Pipelines,” presented at European Offshore Technology Conference and Exhibition held in London, U.K., Oct. 21-24.
  8. Bott, T. and Gudmundsson, J., 1977, “Deposition of paraffin wax from kerosene in cooled heat exchanger tubes,” The Canadian J. of Chemical Engineering, Vol. 55, No. 4, pp. 381-385.
  9. Brower, D.V., Prescott, C.N., Zhang, J., Howerter, C. and Rafferty, D., 2005, “Real-time Flow Assurance Monitoring with Non-Intrusive Fiber Optic Technology,” paper 17376 presented at the Offshore Technology Conference held in Houston, U.S.A., May 2-5.
  10. Brown, T.S., Niesen, V.G. and Erickson, D.D., 1993, ”Measurement and Prediction of the Kinetics of Paraffin Deposition,” paper 26548 presented at 68th SPE Annual Technical Conference and Exhibition held in Houston, U.S.A., Oct. 3-6.
  11. Brown, T.S., Niesen, V.G. and Erickson, D.D., 1994, “The Effects of Light Ends and High Pressure on Paraffin Formation,” paper 28505 presented at the 69th SPE Annual Technical Conference and Exhibition held in New Orleans, U.S.A., Sep. 25-28.
  12. Burger, E.D., Perkins, T.K. and Striegler, J.H., 1981, “Studies of Wax Deposition in the Trans Alaska Pipeline,” J. of Petroleum Technology, Vol. 33, No. 6, pp. 1075-1086.
  13. Carbognani, L., Orea, M. and Fonseca, M., 1999, “Complex Nature of Separated Solid Phases from Crude Oils,” Energy and Fuels, Vol. 13, No. 2, pp. 351-358.
  14. Charles, J.G. and Marcinew, R.P., 1986, “Unique Paraffin Inhibition Technique Reduces Well Maintenance,” J. of Canadian Petroleum Technology, Vol. 25, No. 4, pp. 40-44.
  15. Cole, R.J. and Jessen, F.W., 1960, “Paraffin Deposition”, Oil and Gas Journal, Vol. 58, p. 87.
  16. Craddock, H.A., Mutch, K., Sowerby, K., McGregor, S., Cook, J. and Stranchan, C., 2007, “A Case Study in the Removal of Deposited Wax From a Major Subsea Flowline System in the Gannet Field,” paper 105048 presented at the SPE International Symposium in Oilfield Chemistry held in Houston, U.S.A., Feb. 28-Mar. 2.
  17. Dobbs, B.J., 1999, “A Unique Method of Paraffin Control in Production Operations,“ paper 55647 presented at SPE Rocky Mountain Regional Meeting held in Gillette, U.S.A., May 15-18.
  18. Eaton, F.E. and Weeter, G.Y., 1976, “Paraffin Deposition in Flow Lines,” paper 76-CSME presented at 16th National Heat Transfer Conference held in St. Louis, U.S.A., August.
  19. Erickson, D.D., Niesen, V.G. and Brown, T.S., 1993, “Thermodynamic Measurement and Prediction of Paraffin Precipitation in Crude Oil,” paper 26604 presented at the 68th SPE Annual Technical Conference and Exhibition held in Houston, U.S.A., Oct. 3-6.
  20. Esaklul, K.A., Fung, G., Harrison, G. and Perego, R., 2003, “Active Heating For Flow Assurance Control in Deepwater Flowlines,” paper 15188 presented at Offshore Technology Conference held in Houston, U.S.A., May 5-8.
  21. Fasano, A., Fusi, L. and Correra, S., 2004, “Mathematical Models for Waxy Crude Oils,” Meccanica, Vol. 39, No. 5, pp. 441-482.
  22. Ferworn, K.A., Hammami, A. and Ellis, H., 1997, “Control of Wax Deposition: An Experimental Investigation of Crystal Morphology and an Evaluation of Various Chemical Solvents,” SPE paper 37240 presented at the International Symposium on Oil Field Chemistry held in Houston, U.S.A., Feb. 18-21.
  23. Fleyfel, F., Hernandez, O., Sturgis, R. and Meng, W., 2004, “Evaluation of Pipeline Configurations with Active Heating for Export of Waxy Crude Oil,” paper 90054 presented at SPE Annual Technical Conference and Exhibition held in Houston, U.S.A., Sep. 26-29.
  24. Frenier, W.W., Ziauddin, M. and Venkatesan, R., 2010, Organic Deposits in Oil and Gas Production, SPE, Richardson, U.S.A.
  25. Ghanaei, E., Esmaeilzadeh, F. and Kaljahi, J.F., 2006, “Evaluation of Activity Coefficient Models in Prediction of Wax Appearance Temperature,” paper 101371 presented at the 2006 Abu Dhabi International Petroleum Exhibition and Conference held in Abu Dhabi, U.A.E. Nov. 5-8.
  26. Haddad, S., Simms, G., and Clerk, C., 2003, “Using Multiple Reservoir Measurement to Improve Subsurface Description in Deepwater Gulf of Mexico: King Field,” paper 84380 presented at SPE Annual Technical Conference and Exhibition held in Denver, U.S.A., Oct. 5-8.
  27. Hammami, A. and Raines, M.A., 1999, “Paraffin Deposition from Crude Oils: Comparison of Laboratory Results with Field Data,” SPE Journal, Vol. 4, No. 1, pp. 9-18.
  28. Hammami, A., Ratulowski, J. and Coutinho, J.A.P., 2003, “Cloud Points: Can We Measure or Model Them,” Petroleum Science and Technology, Vol. 21, No. 3-4, pp. 345-358, 2003.
  29. Hsu, J.J., Santamaria, M.M. and Brubaker, J.P., 1994, “Wax Deposition of Waxy Live Crudes under Turbulent Flow Conditions,” paper 28480 presented at 69th SPE Annual Technical Conference and Exhibition held in New Orleans, U.S.A., Sep. 25-28.
  30. Huanquan, P., Abbas, F. and Per, F., 1997, “Pressure and Composition Effect on Wax Precipitation: Experimental Data and Model Results,” SPE Journal, Vol. 12, No. 4, pp. 250-258.
  31. Hunt, J.R. and Elton, B., 1962, “Laboratory Study of Paraffin Deposition,” J. of Petroleum Technology, Vol. 14, No. 11, pp. 1259-1269.
  32. Jennings, W.D. and Newberry, E.W., 2008, “Application of Paraffin Inhibitor Treatment Programs in Offshore Developments,” paper 19154 presented at Offshore Technology Conference held in Houston, U.S.A., May 5-8.
  33. Jessen, F.W. and Howell, J.N., 1958, “Effect of Flow Rate on Paraffin Accumulation in Plastic, Steel, and Coated Pipe,” Petroleum Transactions, Vol. 213, pp. 80-84.
  34. Jorda, R.M., 1966, “Paraffin Deposition and Prevention in Oil Wells,” J. of Petroleum Technology, Vol. 18, No. 12, pp. 1605-1612.
  35. Kulkarni, M.M. and Iyer, K., 2005, “Effects of Pour-point Depressants on Indian Crude Oils,” paper 95976 presented at the SPE Annual Technical Conference and Exhibition held in Dallas, U.S.A., Oct. 9-12.
  36. Kulkarni, V.B., Zhu, T. and Hveding, F., 2008, “Determination and Prediction of Wax Deposition from Alaska North Slope Crude Oil,” IPTC paper 11972 presented at International Petroleum Technology Conference held in Kuala Lumpur, Malaysia, Dec. 3-5.
  37. Lee, H.S., 2008, Computational and Rheological Study of Wax Deposition and Gelation in Subsea Pipelines, PhD thesis, The University of Michigan, U.S.A.
  38. Leontaritis, K.J. and Leontaritis, J.D., 2003, “Cloud Point and Wax Deposition Measurement Techniques,” paper 80267 presented at the SPE International Symposium on Oilfield Chemistry held in Houston, U.S.A., Feb. 5-7.
  39. Lim, J.S., 2010, “Flow Assurance Technology in Petroleum Production System,” J. of Petroleum, Vol. 26, pp. 68-85.
  40. Lim, J.S., Back, S.Y., Kang, P.S., Yu, S.R., Kim, H.S. and Park, J.H., 2012, “Wax Appearance Temperature Measurement of Opaque Oil for Flow Assurance in Subsea Petroleum Production System,” J. of the Korean Society of Marine Engineering, Vol. 36, No. 1, pp.185-194.
  41. Manka, S.J., Magyar, S.J. and Smith, P.R., 1999, “A Novel Method to Winterize Traditional Pour Point Depressants,” paper 56571 presented at SPE Annual Technical Conference and Exhibition held in Houston, U.S.A., Oct. 3-6.
  42. Michel, J. and Adams. E.E., 2005, Oil Spill Dispersants: Efficacy and Effects, The National Academies Press, Washington D.C., U.S.A., pp. 52-53.
  43. Mohammed, A.Y., 2011, “Paraffin Wax Deposition: Mitigation & Removal Techniques,” paper 155412 presented at the SPE Young Professionals Technical Symposium held in Dhahran, Saudi Arabia, Mar. 14-16.
  44. Mokhatab, S. and Wood, D., 2008, “Deepwater risk-1: Challenges risks can be managed in deepwater oil and gas projects,” Oil and Gas Journal, Vol. 104, pp. 37-42.
  45. Monger-McClure, T.G., Tackett, J.E. and Merrill, L.S., 1999, “Comparisons of Cloud Point Measurement and Paraffin Prediction Methods,” SPE Production & Facilities, Vol. 14, pp. 4-16.
  46. NETL, 2008, Evaluation of Wax Deposition and Its Control During Production of Alaska North Slope Oils, DOE Award No. : DE-FC26-01NT41248, Office of Fossil Energy, U.S.A.
  47. Nazar, A., Dabir, B., Vaziri, H. and Islam, M., 2001, “Experimental and Mathematical Modeling of Wax Deposition and Propagation in Pipes Transporting Crude Oil,” SPE paper 67328 presented at the Production and Operations Symposium held in Oklahoma City, U.S.A., Mar. 24-27.
  48. Nghiem, L.X., Kohse, B.F., Fanchi, J.R. and Lake, L.W., 2006, Petroleum Engineering Handbook : Volume Ⅰ General Engineering, SPE, Texas, U.S.A., pp. 397-453.
  49. O’conner, P., Bucknell, J., Lalani, M., Arnold, K.E. and Lake, L.W., 2007, Petroleum Engineering Handbook : Volume Ⅲ Facilities and Construction Engineering, SPE, Richardson, U.S.A., pp. 554-555.
  50. Patton, C.C. and Casad, B.M., 1970, “Paraffin Deposition from Refined Wax-Solvent Systems,” SPE Journal, Vol. 10, No. 1, pp. 17-24.
  51. Pipeline Engineering, 2012. 7. 10, http://www.pipelineengineering.com/field_cleaning.php.
  52. Pipeline Research Limited, 2012. 7. 10, http://www.pipeline-research.com/Dewax%20Frequency.pdf.
  53. Poole, G., Brock, G., Szymczak, S. and Casey, G., 2008, “Successful Pipeline Clean Out-Lessons Learned From Cleaning Paraffin Blockage From a Deepwater Pipeline,” paper 115658 presented at SPE Annual Technical Conference and Exhibition held in Denver, U.S.A., Sep. 21-24.
  54. Rebecca, F.R., 2011, “Direct Electrical Heating of Flowlines – Guide to Uses and Benefits,” paper 22631 presented at Offshore Technology Conference, Rio de Janeiro, Brazil, Oct. 4-6.
  55. Rubel, M.T. and Broussard, D.H., 1994, “Flowline Insulation Thermal Requirements for Deepwater Subsea Pipelines,” paper 28481 presented at SPE Annual Technical Conference and Exhibition held in New Orleans, U.S.A., Sep. 25-28.
  56. Ruschau, G.R., Rogers, R.H., Woodley, S.A. and Wright, E.J., 2010, “Evaluation and Qualification of Materials for Subsea Insulation Systems,” paper 131618 presented at the CPS/SPE International Oil & Gas Conference and Exhibition held in Beijing, China, June 8-10.
  57. Rosvold, K., 2008, Wax Deposition Models, Master thesis, Norwegian University of Science and Technology, Norway.
  58. Sadeghazad, A. and Christiansen, R.L., 1998, “The Effect of Cloud Point Temperature on Wax Deposition,” paper 49467 presented at 8th Abu Dhabi International Petroleum Exhibition and Conference held in Abu Dhabi, U.A.E., Oct. 11-14.
  59. Shecaira, F., Barros, D., Ramachndran, K., Bonin, G. and Waltrich, P., 2011, “The Cottonwood Field Case History : The Pig/Paraffin Obstruction of a Long Subsea, Deepwater Tie-back and Its Successful Remediation,” paper 146156 presented at SPE Annual Technical Conference and Exhibition held in Denver, U.S.A., Oct. 30-Nov. 2.
  60. Singh, P., Venkatesan, R., Fogler, H.S. and Nagarajan, N., 2000, “Formation and Aging of Incipient Thin Film Wax-Oil Gels”, AJChE Journal, Vol. 46, No. 5, pp. 1059-1074.
  61. Singh, P., Venkatesan, R., Fogler, H.S. and Nagarajan, N.R., 2001, “Morphological Evolution of Thick Wax Deposits during Aging”, AJChE Journal, Vol. 47, No. 1, pp. 6-18.
  62. Shell Expro, 2001. 11.12, http://www.alrdc.com/workshops/2001_FallGasLift/presentations.htm.
  63. Stevens, R.S., May, D. and Lake, L.W., 2007, Petroleum Engineering Handbook : Volume Ⅲ Facilities and Construction Engineering, SPE, Texas, U.S.A. pp. 380-387.
  64. Sung, W.M., Kim, S.J., Lee, K.S., and Lim, J.S., 2009, “Korean Petroleum Resources Classification System,” J. of the Korean Society of Geosystem Engineering, Vol. 46, No. 4, pp. 498-508
  65. Svetgoff, J., 1984, “Paraffin Problem Can Be Resolved with Chemicals,” J. of Oil & Gas, Vol. 82, pp. 79-82.
  66. Thant, M.M.M., Sallenhud-Din, M.T., Hewitt, G.F., Hale, C.P. and Quarini, G., 2011, “Mitigating Flow Assurance Challenges in Deepwater Field using Active Heating Methods,” paper 140997 presented at the SPE Middle East Oil and Show and Conference held in Manama, Bahrain, Sep. 25-28.
  67. Todi, S., 2005, Experimental and Modeling Studies of Wax Deposition in Crude Oil Carrying Pipelines, PhD thesis, The University of Utah, U.S.A.
  68. Uba, E., Ikeji, K. and Onyekonwu, M., 2004, “Measurement of Wax Appearance Temperature of an Offshore Live Crude Oil using Laboratory Light Transmission Method,” paper 88963 presented at the 28th Annual SPE International Technical Conference and Exhibition held in Abuja, Nigeria, Aug. 2-4.
  69. Wang, S. and Civan, F., 2001, “Productivity Decline of Vertical and Horizontal Wells by Asphaltene Deposition in Petroleum Reservoirs,” paper 64991 presented at SPE International Symposium on Oilfield Chemistry, Houston, U.S.A., Feb. 13-16.
  70. Wasden, F.K., 2003, “Flow Assurance in Deepwater Flowlines and Pipelines-Challenged Met, Challenges Remaining,” paper 15154 presented at Offshore Technology Conference held in Houston, U.S.A., May 5-8.
  71. Wylde, J.J. and Slayer, L.J., 2012. “Considerations and Lessons Learned on Development of Gas-Lift Paraffin Inhibitors of Subsea Wells in the Gulf of Mexico,” paper 23206 presented at Offshore Technology Conference held in Houston, U.S.A., Apr. 30 - May 3.
Information
  • Publisher :The Korean Society of Mineral and Energy Resources Engineers
  • Publisher(Ko) :한국자원공학회
  • Journal Title :Journal of the Korean Society of Mineral and Energy Resources Engineers
  • Journal Title(Ko) :한국자원공학회지
  • Volume : 50
  • No :2
  • Pages :278-296