Investigation of Bond’s Work Index of Korean Desulfurization Limestone by Ball Mill

doi:10.12972/ksmer.2016.53.2.130

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2016 Vol.53, Issue 2 Preview Page Next Page

Research Paper

Investigation of Bond’s Work Index of Korean Desulfurization Limestone by Ball Mill 볼밀을 활용한 국내 탈황용 석회석의 분쇄일지수 측정: 서준형·백철승·권우택·안지환·조계홍
Jun-Hyung Seo, Chul-Seoung Baek, Woo Teck Kwon, Ji-Whan Ahn and Kye-Hong Cho

30 April 2016. pp. 130-139

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Abstract

In this study, It is secured calibration data for the Bond’s work index of Korean desulfurizationlimestones according to the mining location with the standard-scale ball mill, work index were measured usingJIS M 4002 and KS E 3600. The results, Average work index of limestone are 15.05 kWh/ton in Donghae-Samcheokand 12.44 kWh/ton in Jecheon-Danyang. Jecheon-Danyang limestones were about 20% lower than Donghae-Samcheok limestones. Therefore, besides chemical composition, mining location of limestones has been consideredto influence on the grindability of limestones.

Keywords

Bond’s Work Index

Ball Mill

Limestone

Desulfurization

Energy efficiency

본 연구는 표준규격에 준하는 볼밀을 활용하여 채광 위치에 따른 국내 탈황용 석회석의 분쇄일지수데이터를 확보하고자 하였으며, 분쇄일지수는 JIS M 4002 및 KS E 3600에 준하여 측정하였다. 석회석의 분쇄일지수 측정결과, 동해-삼척지역은 평균 15.05 kWh/ton, 제천-단양지역은 평균 12.44 kWh/ton으로 제천-단양지역석회석이 약 20% 정도 낮은 결과를 나타냄을 확인하였다. 따라서, 화학조성 외에 석회석의 채광위치에도 석회석의 분쇄성은 영향을 미치는 것으로 사료된다.

키워드

분쇄일지수

볼밀

석회석

탈황

에너지효율

References

Angel Irabien., Javier. R. and Immaculada Ortiz., 1990, “Thermal Dehydration of Calcium Hydroxide. 1. Kinetic Model and Parameters,” J. of Industrial and Engineering Chemistry, Vol. 29, No. 8, pp 1599-1606.
Bond, F.C., 1952, “The third theory of comminution.” Transactions of the American Institute of Mining, Metallurgical, and Petroleum Engineers, Vol. 193, No. 4, pp 484-494.
Bond, F.C., 1961, “Crushing and grinding calculations; Part I,” Britisch Chemical Engineering, Vol. 6, No. 6, pp. 378- 385.
Cho, H.C. and Jeong, S., 2005, “A Characteristic Study of Ball Mill and Centrifugal Mill using Discrete Element Method,” J. of Korean Society of Mineral and Energy Resources, Vol. 42, No. 4, pp. 393-402.
Cho, J.S., Yu, Y.H., Choi, M.K., Cho, K.H., Ahn, J.H. and Park, J.K., 2010, “The Effect on Calcination and Hydration Properties of Different Grade Limestone in Danyang Area,” J. of the Korean Society of Mineral and Energy Resources Engineers, Vol. 47, No. 4, pp 487-495.
Choi, S.K., 2002, “Preparation of sub-micron Quartz (Silica) Powder,” Ministry of Trade, Industry and Energy, Gwacheon, Korea, p. 40.
Choi, U.K., Lee, S.H., Cho, S.H., Jeong, S.B., Kim, Y.H. and Park, J.K., 2011, “Characteristics of Degree of Mineral Liberation for Ball Milling Products of Skarn Ore,” J. of Korean Society of Mineral and Energy Resources, Vol. 48, No. 1, pp. 52-58.
Chol, W.K., Jo, H.D., Kim, I.W. and Lee, H.K., 2002, “Effects of Physicochemical Properties of Domestic Limestones on the Dissolution Rates in Flue Gas Desulfurization Process,” J. of the Korean Institute of Chemical Engineers, Vol. 40, No. 3, pp. 404-409.
GICTR(Geological Investigation Corps of Teabaeksan Regian in Korea), 1962, Geological Investigation Report of Taebaeksan Regian, The Geological Society of Korea, p. 107.
Hosten, C. and Avsar, C., 1998, “Grindability of mixtures of cement clinker and trass,” Cement and Concrete Research, Vol. 28, No. 11, pp. 1519-1524.
Ipek, H., Ucbas, Y. and Hosten, C., 2005a, “The bond work index of mixtures of ceramic raw materials,” J of Mineral Engineering, Vol. 18, No. 1, pp. 981-983.
Ipek, H., Ucbas, Y. and Hosten, C., 2005b, “Ternary-mixture grinding of ceramic raw materials,” J. of Mineral Engineering, Vol. 18, No. 2, pp. 45-49.
Irannajad, M., Farzanegan, A. and Razavian, S.M., 2006, “Spreadsheet-based simulation of closed ball milling circuits,” J. of Mineral Engineering, Vol. 19, No. 15, pp. 1495-1504.
Isihara, T., 1964, “Results of Work Index Using an Ordinary Laboratory Ball Mill,” J. of the Mining Institute of Japan, Vol. 80, No. 916, pp. 924-928.
Japanese Industrial Standards Committee (JISC), 1976, JIS M 4002; “Testing Method of Grinding Work Index.” Japan Standards Association (JSA), Japan, pp. 1-8.
Jeong, S.H., Lee, J.J., Choi, S.K., Kim, B.G. and Chung, H.S., 2000, “Dry Grinding Characteristics of Silica Using Stirred Ball Mill,” J. of Korean Society of Mineral and Energy Resources, Vol. 37, No. 2, pp. 100-106.
Jung, K.W., 1999, “Recycling of desulfurizing gypsum,” J. of Korea Limestone Industry Cooperation, Vol. 4, No. 3, pp. 13-30.
KATS(Korea Agency for Technology and Standards)., 2007, “KS A 0507; Testing sieving-General requirements,” Korean Standard Association, Korea, pp. 1-21.
KATS(Korea Agency for Technology and Standards)., 2011, KS E 3600; Testing method of grinding work index, Korean Standard Association, Korea, pp. 1-4.
Kho, C.J., Sohn, J.S. and Sohn, H.J., 1991, “Fine Grinding of Talc using Stirred Ball Mill,” J. of Korean Society of Mineral and Energy Resources, Vol. 28, No. 5, pp. 411-417.
KIGAM(Korea Institute of Geoscience and Mineral Resources), 2009, www.kigam.re.kr.
Kim. S.H., 1987, “Grinding and Separation Techniques in Cement Industry,” J. of the Korean Ceramic Society, Vol. 2, No. 2, pp. 133-144.
KISC(Korea Industrial Standards Commission)., 2001, KS B 2001; Steel Balls for Ball Bearings, Korean Standard Association, Korea, pp. 1-8.
KISC(Korea Industrial Standards Commission)., 2002, KS E 3075; Method for X-ray fluorescence spectrometric analysis of limestone and dolomite, Korean Standard Association, Korea, pp. 1-4.
KLIC(Korea Limestone Industry Cooperation)., 2012, SPS- KLIC-004-775; Limestone for flue gas desulfurization, Korea Limestone Industry Cooperation Standard, Korea, pp. 1-4.
KOMIS(Korea Mineral Resource Information Service), 2015, www.kores.net.
Lee, H. and Cho, H.C., 2002, “Determination of the Breakage Parameters on the Nonmetallic Minerals,” J. of Korean Society of Mineral and Energy Resources, Vol. 39, No. 4, pp. 248-256.
Lee, H. and Cho, H.C., 2006, “Breakage characteristics of some industrial minerals in a ball mill,” J. of Korean Society of Mineral and Energy Resources, Vol. 43, No. 6, pp. 533-542.
Lee, H., Kim, K.H., Kim, W.T. and Kim, S.B., 2013, “Determination of Breakage Parameters in Mathematical Grinding Model by Weight-adjustment Modification,” J. of Korean Society of Mineral and Energy Resources, Vol. 50, No. 1, pp. 80-87.
Miwa, S., 1965, “Some Experimental Studies on the Kinetics of Closed Circuit Grinding,” The Society of Chemical Engineers, Japan, Vol. 29, No. 2, pp. 113-118.
Miwa, S., 1967, “Bond’s Work Index,” J. of the Society of Powder Technology, Japan, Vol. 4, No. 2, pp. 776-785.
Nematollahi, H., 1994, “New size laboratory ball mill for Bond Work Index determination,” J. of Mining Engineering, Vol. 46, No. 4, pp. 352-353.
Noh, J.H. and Lee, N.K., 2007, “Applied-mineralogical Study on the Grinding Effects and Powder Properties of High- Ca Limestone,” J. of the Korean Society of Mineral and Energy Resources Engineers, Vol. 44, No. 3, pp. 191-207.
Oner, M., 2000, “A study of intergrinding and separate grinding of blast furnace slag cement,” J. of Ceramic Concrete Research, Vol. 30, No. 3, pp. 473-480.
Park, S.S., Kim, K.H. and Park, S.Y., 1997, “Grindability and Reactivity of Limestones for Flue Gas Desulfurization,” J. of the Korean Society of Industrial and Engineering Chemistry, Vol. 1, No. 2, pp. 465-468.
Seo, J.H., Baek, C.S., Kwon, W.T., Cho, K.H. and Ahn, J.H., 2015: “Influence of Physicochemical Characteristic of Donghae-Samcheok Limestones on the Performance of Flue Gas Desulfurization(FGD),” J. of Korean Institute of Resources Recycling, Vol. 24, No. 6, pp. 38-44.
Sim, C.H. 1992, “Manipulate variable of dry grinding with small ball mill,” Journal of the Korean Ceramic Society, Vol. 7, No. 4, pp. 436-442.
Sim, C.H., 1987, “Investigation of a Method Measuring Bond’s Work Index of Korean Kaolin by Laboratory Ball Mill,” J. of the Korean Ceramic Society, Vol. 24, No. 1, pp. 47-55.
Sim. C.H. 1999, “The Effect of Operating Variables on the Ball Milling of Quartz Sand.” J. of Korean Society of Mineral and Energy Resources, Vol. 36, No. 6, pp. 463-469.
Sim. C.H. and Oh, S.K., 2000, “FORTRAN Program for the Calculation of Bond’s Grinding Work Index,” J. of the Korean Society of Mineral and Energy Resources Engineers, Vol. 37, No. 5, pp. 377-383.
Srivastava, R.K. and Jozewicz, W., 2001, “Flue Gas Desulfurization : The State of the Art,” J of the Air and Waste Management Assiciation, Vol. 51, No. 12, pp. 1676-1688.

Information

Publisher :The Korean Society of Mineral and Energy Resources Engineers
Publisher(Ko) :한국자원공학회
Journal Title :Journal of the Korean Society of Mineral and Energy Resources Engineers
Journal Title(Ko) :한국자원공학회지
Volume : 53
No :2
Pages :130-139
DOI :https://doi.org/10.12972/ksmer.2016.53.2.130

[1] Angel Irabien., Javier. R. and Immaculada Ortiz., 1990, “Thermal Dehydration of Calcium Hydroxide. 1. Kinetic Model and Parameters,” J. of Industrial and Engineering Chemistry, Vol. 29, No. 8, pp 1599-1606.

[2] Bond, F.C., 1952, “The third theory of comminution.” Transactions of the American Institute of Mining, Metallurgical, and Petroleum Engineers, Vol. 193, No. 4, pp 484-494.

[3] Bond, F.C., 1961, “Crushing and grinding calculations; Part I,” Britisch Chemical Engineering, Vol. 6, No. 6, pp. 378- 385.

[4] Cho, H.C. and Jeong, S., 2005, “A Characteristic Study of Ball Mill and Centrifugal Mill using Discrete Element Method,” J. of Korean Society of Mineral and Energy Resources, Vol. 42, No. 4, pp. 393-402.

[5] Cho, J.S., Yu, Y.H., Choi, M.K., Cho, K.H., Ahn, J.H. and Park, J.K., 2010, “The Effect on Calcination and Hydration Properties of Different Grade Limestone in Danyang Area,” J. of the Korean Society of Mineral and Energy Resources Engineers, Vol. 47, No. 4, pp 487-495.

[6] Choi, S.K., 2002, “Preparation of sub-micron Quartz (Silica) Powder,” Ministry of Trade, Industry and Energy, Gwacheon, Korea, p. 40.

[7] Choi, U.K., Lee, S.H., Cho, S.H., Jeong, S.B., Kim, Y.H. and Park, J.K., 2011, “Characteristics of Degree of Mineral Liberation for Ball Milling Products of Skarn Ore,” J. of Korean Society of Mineral and Energy Resources, Vol. 48, No. 1, pp. 52-58.

[8] Chol, W.K., Jo, H.D., Kim, I.W. and Lee, H.K., 2002, “Effects of Physicochemical Properties of Domestic Limestones on the Dissolution Rates in Flue Gas Desulfurization Process,” J. of the Korean Institute of Chemical Engineers, Vol. 40, No. 3, pp. 404-409.

[9] GICTR(Geological Investigation Corps of Teabaeksan Regian in Korea), 1962, Geological Investigation Report of Taebaeksan Regian, The Geological Society of Korea, p. 107.

[10] Hosten, C. and Avsar, C., 1998, “Grindability of mixtures of cement clinker and trass,” Cement and Concrete Research, Vol. 28, No. 11, pp. 1519-1524.

[11] Ipek, H., Ucbas, Y. and Hosten, C., 2005a, “The bond work index of mixtures of ceramic raw materials,” J of Mineral Engineering, Vol. 18, No. 1, pp. 981-983.

[12] Ipek, H., Ucbas, Y. and Hosten, C., 2005b, “Ternary-mixture grinding of ceramic raw materials,” J. of Mineral Engineering, Vol. 18, No. 2, pp. 45-49.

[13] Irannajad, M., Farzanegan, A. and Razavian, S.M., 2006, “Spreadsheet-based simulation of closed ball milling circuits,” J. of Mineral Engineering, Vol. 19, No. 15, pp. 1495-1504.

[14] Isihara, T., 1964, “Results of Work Index Using an Ordinary Laboratory Ball Mill,” J. of the Mining Institute of Japan, Vol. 80, No. 916, pp. 924-928.

[15] Japanese Industrial Standards Committee (JISC), 1976, JIS M 4002; “Testing Method of Grinding Work Index.” Japan Standards Association (JSA), Japan, pp. 1-8.

[16] Jeong, S.H., Lee, J.J., Choi, S.K., Kim, B.G. and Chung, H.S., 2000, “Dry Grinding Characteristics of Silica Using Stirred Ball Mill,” J. of Korean Society of Mineral and Energy Resources, Vol. 37, No. 2, pp. 100-106.

[17] Jung, K.W., 1999, “Recycling of desulfurizing gypsum,” J. of Korea Limestone Industry Cooperation, Vol. 4, No. 3, pp. 13-30.

[18] KATS(Korea Agency for Technology and Standards)., 2007, “KS A 0507; Testing sieving-General requirements,” Korean Standard Association, Korea, pp. 1-21.

[19] KATS(Korea Agency for Technology and Standards)., 2011, KS E 3600; Testing method of grinding work index, Korean Standard Association, Korea, pp. 1-4.

[20] Kho, C.J., Sohn, J.S. and Sohn, H.J., 1991, “Fine Grinding of Talc using Stirred Ball Mill,” J. of Korean Society of Mineral and Energy Resources, Vol. 28, No. 5, pp. 411-417.

[21] KIGAM(Korea Institute of Geoscience and Mineral Resources), 2009, www.kigam.re.kr.

[22] Kim. S.H., 1987, “Grinding and Separation Techniques in Cement Industry,” J. of the Korean Ceramic Society, Vol. 2, No. 2, pp. 133-144.

[23] KISC(Korea Industrial Standards Commission)., 2001, KS B 2001; Steel Balls for Ball Bearings, Korean Standard Association, Korea, pp. 1-8.

[24] KISC(Korea Industrial Standards Commission)., 2002, KS E 3075; Method for X-ray fluorescence spectrometric analysis of limestone and dolomite, Korean Standard Association, Korea, pp. 1-4.

[25] KLIC(Korea Limestone Industry Cooperation)., 2012, SPS- KLIC-004-775; Limestone for flue gas desulfurization, Korea Limestone Industry Cooperation Standard, Korea, pp. 1-4.

[26] KOMIS(Korea Mineral Resource Information Service), 2015, www.kores.net.

[27] Lee, H. and Cho, H.C., 2002, “Determination of the Breakage Parameters on the Nonmetallic Minerals,” J. of Korean Society of Mineral and Energy Resources, Vol. 39, No. 4, pp. 248-256.

[28] Lee, H. and Cho, H.C., 2006, “Breakage characteristics of some industrial minerals in a ball mill,” J. of Korean Society of Mineral and Energy Resources, Vol. 43, No. 6, pp. 533-542.

[29] Lee, H., Kim, K.H., Kim, W.T. and Kim, S.B., 2013, “Determination of Breakage Parameters in Mathematical Grinding Model by Weight-adjustment Modification,” J. of Korean Society of Mineral and Energy Resources, Vol. 50, No. 1, pp. 80-87.

[30] Miwa, S., 1965, “Some Experimental Studies on the Kinetics of Closed Circuit Grinding,” The Society of Chemical Engineers, Japan, Vol. 29, No. 2, pp. 113-118.

[31] Miwa, S., 1967, “Bond’s Work Index,” J. of the Society of Powder Technology, Japan, Vol. 4, No. 2, pp. 776-785.

[32] Nematollahi, H., 1994, “New size laboratory ball mill for Bond Work Index determination,” J. of Mining Engineering, Vol. 46, No. 4, pp. 352-353.

[33] Noh, J.H. and Lee, N.K., 2007, “Applied-mineralogical Study on the Grinding Effects and Powder Properties of High- Ca Limestone,” J. of the Korean Society of Mineral and Energy Resources Engineers, Vol. 44, No. 3, pp. 191-207.

[34] Oner, M., 2000, “A study of intergrinding and separate grinding of blast furnace slag cement,” J. of Ceramic Concrete Research, Vol. 30, No. 3, pp. 473-480.

[35] Park, S.S., Kim, K.H. and Park, S.Y., 1997, “Grindability and Reactivity of Limestones for Flue Gas Desulfurization,” J. of the Korean Society of Industrial and Engineering Chemistry, Vol. 1, No. 2, pp. 465-468.

[36] Seo, J.H., Baek, C.S., Kwon, W.T., Cho, K.H. and Ahn, J.H., 2015: “Influence of Physicochemical Characteristic of Donghae-Samcheok Limestones on the Performance of Flue Gas Desulfurization(FGD),” J. of Korean Institute of Resources Recycling, Vol. 24, No. 6, pp. 38-44.

[37] Sim, C.H. 1992, “Manipulate variable of dry grinding with small ball mill,” Journal of the Korean Ceramic Society, Vol. 7, No. 4, pp. 436-442.

[38] Sim, C.H., 1987, “Investigation of a Method Measuring Bond’s Work Index of Korean Kaolin by Laboratory Ball Mill,” J. of the Korean Ceramic Society, Vol. 24, No. 1, pp. 47-55.

[39] Sim. C.H. 1999, “The Effect of Operating Variables on the Ball Milling of Quartz Sand.” J. of Korean Society of Mineral and Energy Resources, Vol. 36, No. 6, pp. 463-469.

[40] Sim. C.H. and Oh, S.K., 2000, “FORTRAN Program for the Calculation of Bond’s Grinding Work Index,” J. of the Korean Society of Mineral and Energy Resources Engineers, Vol. 37, No. 5, pp. 377-383.

[41] Srivastava, R.K. and Jozewicz, W., 2001, “Flue Gas Desulfurization : The State of the Art,” J of the Air and Waste Management Assiciation, Vol. 51, No. 12, pp. 1676-1688.

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