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2018 Vol.55, Issue 6 Preview Page

Review

Recent Trends and Prospects of Chemical Enhanced Oil Recovery

석유회수증진을 위한 화학적 공법 연구 동향 및 전망

Youngil Choi1
,
Pan-Sang Kang1
,
Jong-Se Lim1*
최 영일1
,
강 판상1
,
임 종세1*
1한국해양대학교 에너지자원공학과
* Corresponding Author
31 December 2018. pp. 660-669
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Abstract

Enhanced oil recovery (EOR) is a method used to improve the recovery factor of remaining hydrocarbon in reservoir. Polymer and surfactant EOR techniques have limitations depending on reservoir or production conditions (temperature, salinity, etc.) because the polymer and surfactant are highly affected by the reservoir conditions. In this study, analysis of the current improvements to chemical substances and application technologies was performed based on recent research data. Conventional polymer is readily degraded by the conditions of high temperature and high salinity. Therefore, new polymers and injection techniques have been developed to remediate such problems. In addition, surfactant applicable to shale and carbonate reservoirs is developed as petroleum recovery expands to unconventional reservoirs. However, these chemical substances are not widely used in the current oil fields due to high costs. Therefore, further studies must be conducted to reduce the cost and thus increase the effectiveness of EOR techniques.

Keywords
Enhanced oil recovery
Chemical method
Polymer
Surfactant

석유회수증진법은 저류층 내의 잔존 석유의 회수율을 높이는 기술로 그 종류가 다양하다. 이 중 화학적 공법에 사용되는 폴리머, 계면활성제는 온도, 염도 등에 영향을 받으므로 적용할 수 있는 저류층이나 생산조건에 제약이 있다. 이 연구에서는 최근 연구 자료를 기반으로 화학적 공법의 문제해결과 효율 향상을 위한 기술 개발에 대해 분석하였다. 고온 및 고염 조건에서 분해가 쉽게 발생하는 기존의 폴리머를 개선하기 위해 새로운 폴리머 및 주입법 기술이 개발되었고 석유회수증진이 비전통저류층으로 활용 범위를 확대함에 따라 셰일과 탄산염암 저류층에 적용 가능한 계면활성제 개발이 이루어지고 있다. 하지만 이러한 화학물질은 비용이 높아 아직까지 현장에서는 널리 활용되어지지 않고 있으며 추가적인 연구를 통해 비용을 절감할 수 있다면 석유회수증진을 위해 효과적으로 적용될 것이다.

키워드
석유회수증진법
화학적 공법
폴리머
계면활성제
References
1
Abdel-Fattah, A.I., Mashat, A., Alaskar, M., and Gizzatov, A., 2017. NanoSurfactant for EOR in Carbonate Reservoirs. SPE Kingdom of Saudi Arabia Annual Technical Symposium and Exhibition, SPE, Dammam, Saudi Arabia, 8p.
10.2118/188046-MS
2
Alexey, A., Li, E., Yang, L., and Wu, F., 2018. Comparison of Different Polymers Flooding with Fresh and Produced Water in Pu I Layer of Daqing Oilfield. SPE EOR Conference at Oil and Gas West Asia, SPE, Muscat, Oman, 12p.
3
AlGeer, M.A., Alshehri, A.J., and AlKhatib, A.M., 2016. Impact of Chemical Flood Implementation Time on Ultimate Recovery and Net Present Value. SPE Kingdom of Saudi Arabia Annual Technical Symposium and Exhibition, SPE, Dammam, Saudi Arabia, 14p.
10.2118/182791-MS
4
Alhashim, H.W., Wang, J., AlSofi, A.M., and Kaidar, Z.F., 2018. Gelation Time Optimization of an Organically Crosslinked Polyacrylamide Gel System for In-Depth Fluid Diversion Application. SPE EOR Conference at Oil and Gas West Asia, SPE, Muscat, Oman, 10p.
5
Al-Murayri, M.T., Al-Mayyan, H.E., Moudi, K., Al-Ajmi, F., Pitts, D., Wyatt, M.J., French, K., and Surtek, J., 2018. Chemical EOR Economic Evaluation in a Low Oil Price Environment: Sabriyah Lower Burgan Reservoir Case Study. SPE EOR Conference, SPE, Muscat, Oman, 11p.
6
AlSofi, A.M., Wang, J., AlBoqmi, A.M., AlOtaibi, M.B., Ayirala, S.C., and AlYousef, A.A., 2016. Smartwater Synergy with Chemical EOR for a Slightly Viscous Arabian Heavy Reservoir. SPE Heavy Oil Conference and Exhibition, SPE, Kuwait City, Kuwait, 11p.
7
Ayirala, S.C., Uehara-Nagamine, E., Matzakos, A.N., Chin, R.W., Doe, P.H., and Van den Hoek, P.J., 2010. A Designer Water Process for Offshore Low Salinity and Polymer Flooding Applications. SPE Improved Oil Recovery Symposium, SPE, Tulsa, Oklahoma, U.S.A., 12p.
10.2118/129926-MS
8
Bansal, V.K. and Shah, D.O., 1977. The effect of addition of ethoxylated sulfonate on salt tolerance, optimal salinity and impedence characteristics of petroleum sulfonate solutions. J. Colloid and Interface Science, 65(3), 451-459.
10.1016/0021-9797(78)90096-6
9
Bourbiaux, B., Rosenberg, E., Robin, M., Chabert, M., Chevallier, E., and Gautier, S., 2017. Computed-Tomography-Scan Monitoring of Foam-Based Chemical-Enhanced-Oil-Recovery Processes in Fractured Carbonate Cores. SPE EOR Conference at Oil and Gas West Asia, SPE, Muscat, Oman, 12p.
10
Chahardowli, M., Farajzadeh, R., and Bruining, H., 2016. Experimental investigation of dimethyl ether/polymer hybrid as an enhanced oil recovery method. SPE EOR Conference at Oil and Gas West Asia, SPE, Muscat, Oman, 16p.
11
Chang, H.L., 1978. Polymer flooding technology-yesterday, today and tomorrow. J. Petroleum Technology, 30(8), 1113-1128.
10.2118/7043-PA
12
Chang, H.L., Zhang, Z.Q., Wang, Q.M., Xu, Z.S., Guo, Z.D., Sun, H.Q., Cao, X.L., and Qiao, Q., 2006. Advances in polymer flooding and alkaline/surfactant/polymer processes as developed and applied in the people's republic of China. J. Petroleum Technology, 58(2), 84-89.
10.2118/89175-JPT
13
Chevalier, T., Labaume, J., Gautier, S., Chevallier E., and Chabert M., 2018. A Novel Experimental Approach for Accurate Evaluation of Chemical EOR Processes in Tight Reservoir Rocks. SPE Improved Oil Recovery Conference, SPE, Tulsa, Oklahoma, U.S.A., 12p.
10.2118/190171-MS
14
Chidinma, U., Onyekonwu, M., and Akaranta, O., 2016. Alkaline-Surfactant Flooding in Niger-Delta: An Experimental Approach. SPE Nigeria Annual International Conference and Exhibition, SPE, Lagos, Nigeria, 11p.
15
Choi, S.K., 2008. pH Sensitive Polymers for Novel Conformance Control and Polymer Flooding Applications. PhD Thesis, The University of Texas at Austin, Austin, Texas, U.S.A., 314p.
16
Delamaide, E., Bazin, B., and Rousseau, D., 2014. Chemical EOR for Heavy Oil: the Canadian Experience. SPE EOR Conference, SPE, Muscat, Oman, 31p.
17
Doe, P.H., Moradi-Araghi, A., Shaw, J.E., and Stahl, G.A., 1987. Development and evaluation of EOR polymers suitable for hostile environments part 1: copolymers of vinylpyrrolidone and acrylamide. J. SPE Reservoir Engineering, 2(4), 461-467.
10.2118/14233-PA
18
Fortenberry, R.P., Kim, D.H., Nizamidin, N., Adkins, S., Pinnawala Arachchilage, G.W.P., Koh, H.S. Weerasooriya, U.P., and Pope, G.A., 2013. Use of Co-Solvents to Improve Alkaline-Polymer Flooding. SPE Annual Technical Conference and Exhibition, SPE, New Orleans, Louisiana, U.S.A., 24p.
19
Fredriksen, S.B., Alcorn, Z.P., Frøland, A., Viken A., Rognmo, A.U., Seland, J.G., Ersland, G., Fernø, M.A., and Graue, A., 2018. Surfactant Pre-Floods during CO2 Foam for Integrated Enhanced Oil Recovery in Fractured Oil-Wet Carbonates. SPE Improved Oil Recovery Conference, SPE, Tulsa, Oklahoma, U.S.A., 19p.
20
Goudarzi, A., Almohsin, A., Varavei, A., Delshad, M., Bai, B., and Sepehrnoori, K., 2014. New Experiments and Models for Conformance Control Microgels. SPE Improved Oil Recovery Symposium, SPE, Tulsa, Oklahoma, U.S.A., 17p.
10.2118/169159-MS
21
Hassan, A.M., and Al-Hashim, H.S., 2016. Cost Effective Chelating Agent EOR Fluid System for Carbonate Reservoirs. SPE Kingdom of Saudi Arabia Annual Technical Symposium and Exhibition, SPE, Dammam, Saudi Arabia, 19p.
10.2118/182788-MS
22
Henthorne, L., Pope, G.A., Weerasooriya, U., and Llano, V., 2014. Impact of Water Softening on Chemical Enhanced Oil Recovery Project Economics. SPE Improved Oil Recovery Symposium, SPE, Tulsa, Oklahoma, U.S.A., 12p.
10.2118/169165-MS
23
Jennings, R.R., Rogers, J.H., and West, T.J., 1971. Factors influencing mobility control by polymer solutions. J. Petroleum Technology, 23(3), 391-401.
10.2118/2867-PA
24
Jewett, R.L. and Schurz, G.F., 1970. Polymer flooding-a current appraisal. J. Petroleum Technology, 22(6), 675-684.
10.2118/2545-PA
25
Kaiser, A., Curren, M., Parmenter, D., Mahmoudkhani, A., and Wylde, J., 2016. A New Class of Renewable Surfactants for Chemical Enhanced Oil Recovery. SPE Annual Technical Conference and Exhibition, SPE, Dubai, UAE, 9p.
10.2118/181290-MS
26
Kalwar, S.A., Elraies, K.A., Abbas, G., Kumar, S., and Farouque, K., 2016. AASP flooding as a Substitute of ASP Flooding for Chemical EOR in Carbonate Reservoir. PAPG/SPE Pakistan Section Annual Technical Conference and Exhibition, SPE, Islamabad, Pakistan, 11p.
10.2118/185313-MS
27
Kang, P.S. and Lim, J.S., 2011. Development of artificial neural network viscosity model of pH-sensitive polymer for enhanced oil recovery. J. Korean Society of Mineral Energy Resources Engineers, 48(2), 190-198.
28
Kang, P.S., Lim, J.S., and Huh, C., 2016. Screening criteria and consideration of offshore enhanced oil recovery. Energies, 9(1), 1-18.
10.3390/en9010044
29
Kim, J., Gomaa, A.M., Nelson, S.G., and Hudson, H.G., 2016. Engineering Hydraulic Fracturing Chemical Treatment to Minimize Water Blocks: A Simulated Reservoir-on-a-Chip Approach. SPE International Conference &; Exhibition on Formation Damage Control, SPE, Lafayette, Louisiana, U.S.A., 16p.
10.2118/178959-MS
30
Koh, H., 2015. Experimental Investigation of the Effect of Polymers on Residual Oil Saturation, PhD. Thesis, The University of Texas at Austin, Austin, Texas, U.S.A., 282p.
31
Lake, L.W., 1989. Enhanced Oil Recovery. Eaglewood Cliffs, U.S.A., p.1.
32
Lee, K.S., 2010. Comparison of reservoir performances for chemical enhanced oil recovery. J. Korean Society of Mineral Energy Resources Engineers, 47(3), 291-299.
33
Lee, H.S., Ki, S.I, Choi, Y.I., and Lim, J.S., 2018. Theoretical considerations and case study on application of cyclic gas injection in U.S. eagle ford shale reservoir. J. Korean Society of Mineral Energy Reserouces Engineers, 55(3), 238-245.
10.32390/ksmer.2018.55.3.238
34
Lu, J., Britton, C., Solairaj, S., Liyanage, P.J., Kim, D.H., Adkins, S., and Pope, G.A., 2012. Novel Large-Hydrophobe Alkoxy Carboxylate Surfactants for Enhanced Oil Recovery. Eighteenth SPE Improved Oil Recovery Symposium, SPE, Tulsa, Oklahoma, U.S.A., 22p.
10.2118/154261-MS
35
Luo, J.H., Bu, R.Y., Wang, P.M., Bai, F.L., Zhang, Y., Yang, J.B., and Liu, Y.Z., 2002. Properties of Kypam, a salinity-resistant polymer used in EOR. Oilfield Chemistry, 9(1), 64-67.
36
Manrique, E.J., Muci, V.E., and Gurfinkel, M.E., 2006. EOR Field Experiences in Carbonate Reservoirs in the United States. SPE/DOE Symposium on Improved Oil Recovery, SPE, Tulsa, Oklahoma, U.S.A., 22p.
10.2118/100063-MS
37
Moslemizadeh, A., Dehkordi, A.F., Barnaji, M.J., Naseri, M., Ravi, S.G., and Jahromi, E.K., 2016. Novel bio-based surfactant for chemical enhanced oil recovery in montmorillonite rich reservoirs: adsorption behavior, interaction impact, and oil recovery studies. J. Chemical Engineering Research and Design, 109, 18-31.
10.1016/j.cherd.2016.01.007
38
Parsons, C., Chernetsky, A., Eikmans, D., Riele, P., Boersma, D., Sersic, I., and Broos, R., 2016. Introducing a Novel Enhanced Oil Recovery Technology. SPE Improved Oil Recovery Conference, SPE, Tulsa, Oklahoma, U.S.A., 10p.
10.2118/179560-MS
39
Pye, D.J., 1964. Improved secondary recovery by control of water mobility. J. Petroleum Technology, 16(8), 911-916.
10.2118/845-PA
40
Raffa, P., Broekhuis, A. A., and Picchioni, F., 2016. Polymeric surfactants for enhanced oil recovery: A review. J. Petroleum Science and Engineering, 145, 723-733.
10.1016/j.petrol.2016.07.007
41
Sharma, H., Panthi, K., Ghosh, P., Weerasooriya, U., and Mohanty, K., 2018. Novel Surfactants without Hydrocarbon Chains for Chemical EOR. SPE Improved Oil Recovery Conference, SPE, Tulsa, Oklahoma, U.S.A., 24p.
10.2118/190232-MS
42
Sheng, J.J., 2011. Modern Chemical Enhanced Oil Recovery: Theory and Practice (1st Ed.), Gulf Professional Publishing, Burlington, U.S.A., p.207-238.
10.1016/B978-1-85617-745-0.00006-1
43
Shuler, P.J., Lu, Z., Ma, Q., and Tang, Y., 2016. Surfactant Huff-n-Puff Application Potentials for Unconventional Reservoirs. SPE Improved Oil Recovery Conference, SPE, Tulsa, Oklahoma, U.S.A., 14p.
10.2118/179667-MS
44
Standnesa, D.C. and Skjevrakb, I., 2014. Literature review of implemented polymer field projects. J. Petroleum Science and Engineering, 122, 761-775.
10.1016/j.petrol.2014.08.024
45
Sung, W.M., Bae, W.S., Choi, J.G., Lee, K.S., Lim, J.S., Kwon, S.I., Chun, B.H., and Huh, D.G., 2014. Petroleum Engineering (1st Ed.), CIR, Seoul, Korea, p.252-253.
46
Taber, J.J., Martin, F.D., and Seright, R.S., 1997a. EOR screening criteria revisited-part 1: introduction to screening criteria and enhanced recovery field projects. J. SPE Reservoir Engineering, 12(3), 189-198.
10.2118/35385-PA
47
Taber, J.J., Martin, F.D., and Seright, R.S., 1997b. EOR screening criteria revisited-part 2: applications and impact of oil prices. J. SPE Reservoir Engineering, 12(3), 199-205.
10.2118/39234-PA
48
Tagavifar, M., Fortenberry, R., Rouffignac, E., Sepehrnoori, K., and Pope, G.A., 2016. Heavy-oil recovery by combined hot water and alkali/cosolvent/polymer flooding. SPE J., 21(1), 74-86.
10.2118/170161-PA
49
Taylor, K.C. and Nasr-El-Dinb, H.A., 1998. Water-soluble hydrophobically associating polymers for improved oil recovery: A literature review. J. Petroleum Science and Engineering, 19, 265-280.
10.1016/S0920-4105(97)00048-X
50
Walker, D., Britton, C., Kim, D.H., Dufour, S., Weerasooriya, U., and Pope, G.A., 2012. The Impact of Microemulsion Viscosity on Oil Recovery. SPE Improved Oil Recovery Symposium, SPE, Tulsa, Oklahoma, U.S.A., 13p.
10.2118/154275-MS
51
Wang, D., Chen, J., and Wu, J., 2002. Producing by Polymer Flooding More Than 300 Million Barrels of Oil, What Experiences Have Been Learnt?. SPE Asia Pacific Oil and Gas Conference and Exhibition, SPE, Melbourne, Australia, 9p.
52
Wang, Q., Al-Nasser, W., Al-Dawood, F., Al-Shafai, T., Al-Badairy, H., Shen, S., Al-Ajwad, H., and Liang, F., 2017. Inhibition of Calcium Carbonate Scale in the Presence of EOR Chemicals. SPE International Conference on Oilfield Chemistry, SPE, Montgomery, Texas, U.S.A., 14p.
10.2118/184534-MS
53
Wu, X., Yang, Z., Xu, H., Zhang L., Xiong C., Yang, H., Shao, L., Kang, B., Fu, Y., Tian, X., and Cao, H., 2016. Success and Lessons Learned from Polymerflooding a Ultra High Temperature and Ultra High Salinity Oil Reservoir - A Case Study from West China. SPE Improved Oil Recovery Conference, SPE, Tulsa, Oklahoma, U.S.A., 10p.
54
Zeng, T., Miller, C.S., and Mohanty, K., 2018. Application of Surfactants in Shale Chemical EOR at High Temperatures. SPE Improved Oil Recovery Conference, SPE, Tulsa, Oklahoma, U.S.A., 14p.
10.2118/190318-MS
55
Zhang, X., Li, X., Guo, S., Sun, G., and Guan, W., 2016. A Unique Anti-Salt Polymer for EOR. SPE Asia Pacific Oil & Gas Conference and Exhibition, SPE, Perth, Australia, 7p.
56
Zhu, D., Hou, J., Wei, Q., and Chen, Y., 2017. Development of a High-Temperature-Resistant Polymer-Gel System for Conformance Control in Jidong Oil Field. SPE/IATMI Asia Pacific Oil & Gas Conference and Exhibition, SPE, Jakarta, Indonesia, 10p.
Information
  • Publisher :The Korean Society of Mineral and Energy Resources Engineers
  • Publisher(Ko) :한국자원공학회
  • Journal Title :Journal of the Korean Society of Mineral and Energy Resources Engineers
  • Journal Title(Ko) :한국자원공학회지
  • Volume : 55
  • No :6
  • Pages :660-669
  • Received Date : 2018-11-13
  • Revised Date : 2018-12-14
  • Accepted Date : 2018-12-20
  • DOI :https://doi.org/10.32390/ksmer.2018.55.6.660
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