Adsorption of Fluoride Onto Granular Ferric Hydroxide

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2008 Vol.45, Issue 5 Preview Page Next Page

Adsorption of Fluoride Onto Granular Ferric Hydroxide GFH(Granular Ferric Hydroxide)를 이용한 불소 흡착연구: 정우식, 지민규, 이상훈, Eva Kumar, Amit Bhatn, 김선준, 전병훈
Woo-Sik Jung, Min-Kyu Ji, Sang-Hun Lee, Eva Kumar, Amit Bhatnagar, Sun-Joon Kim and Byong-Hun Jeon

31 October 2008. pp. 441-447

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Abstract

The present study was undertaken to evaluate the adsorption potential of Granular Ferric Hydroxide (GFH) for fluoride removal from water by batch mode. The adsorption capacity of GFH for fluoride was found 0.052 mmol/g at 25℃. The kinetic data reveal that uptake rate of fluoride on GFH was fast in the beginning, and 50% adsorption was occurred within 5 minutes. The equilibrium time for maximum uptake of fluoride on GFH was about 30 minutes. Two simplified kinetic models namely (i) Lagergren’s pseudo-first-order model and (ii) Weber and Morris intraparticle diffusion model were tested to describe the adsorption mechanism. It was found that the present system of fluoride adsorption on GFH was well described with pseudo-first-order kinetic model. The intraparticle diffusion model suggests that the mechanism of fluoride adsorption onto GFH is complex and surface adsorption as well as intraparticle diffusion contribute to the actual adsorption process.

Keywords

Fluoride pollution

Adsorption

Granular Ferric Hydroxide (GFH)

pseudo-first-order kinetic model

intraparticle diffusion kinetic model

Granular Ferric Hydroxide(GFH)의 불소제거제로의 적용가능성을 알아보기 위해 10 mg/L의 불소농도 조건에서 GFH의 불소 흡착능력을 평가하였다. GFH의 불소 흡착은 반응초기에 빠르게 진행되어 5분 이내에 흡착율이 50%에 이르렀고 30분 이내에 흡착평형에 이르렀다. 또한, GFH의 불소 흡착량은 0.052 mmol/g이었고 흡착 결과는 Langmuir 흡착등온식으로 가장 적합하게 모사되었다. 흡착 메커니즘을 규명하기 위하여 간단한 속도 모델인 Lagergren의 pseudo-first-order model과 Weber와 Morris의 intraparticle diffusion model을 적용하였다. GFH를 이용한 불소 흡착시스템은 pseudo-first-order model로 잘 설명되고, intraparticle diffusion model을 통해 잘 설명된다. 불소가 GFH에 흡착될 때, 표면에 흡착될 뿐만 아니라 GFH 입자 내로의 분산도 일어나는 것으로 나타났다.

키워드

불소 오염

흡착

GFH

유사-일차 속도모델

입자내 확산 모델

References

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정기영, 김강주, 김종용, 박재형, 이도영, 박순길, 2003, “포항-경주지역 양산단층대 주변의 고불소 지하수 산출 특 성,” 지질학회지, 39권, 3호, pp. 371-384.
수자원환경, 1995, “불소의 정체를 밝힌다,” Vol. 79, pp.22-30.
환경부, 2006, 2006 하반기 민,관합동 수질검사결과.
Adhikary, S.K., Tipnis, U.K., Harkare, W.P., and Govindan, K.P., 1989, “Defluoridation during desalination of brackish water by electrodialysis,” Desalination, Vol. 71, No. 3, pp. 301-312.
Apambire, W.B., Boyle, D.R. and Michel, F.A., 1997, “Geochemistry, genesis, and health implications of fluoriferous groundwaters in the upper regions Ghana,” Environmental Geology, Vol. 33, No. 1, pp. 13-24.
Banks, D., Reimann, C., Rǿyset, O., Skarphagen, H., and Saether, O.M., 1995, “Natural concentrations of major and trace elements in some Norwegian bedrock groundwaters,” Appl. Geochem, Vol. 10, No. 1, pp. 1-16.
Benefield, L. D., Joseph, F., Judkins, JR, Barron L. Weand, 1982, “Process Chemistry for water and wastewater treatment,” Prentice-Hall, inc.
Cox, G. J., 1939, “New knowledge of Fluorine in relation to dental caries,” J. Am. Water Works Assoc., Vol. 31, pp. 1926-1930.
CDC (Centers for Disease Control and Prevention), 1999, Achievements in Public Health, 1900-1999: Fluoridization of drinking water to prevent dental caries. Morbidity and Mortality Weekly Report, 48, pp. 933-940.
Dean, H.T., 1934, “Classification of mottled enamel diagnosis,” J. Am. Dent. Assoc., Vol. 12, pp. 1421-1426.
Driehaus, W., 2002, “Arsenic removal - experience with the GEHⓇ process in Germany,” Water Supply, Vol. 2, No.2, pp. 275-280.
Ghorai, S. and Pant, K.K., 2005, “Equilibrium, kinetics and breakthrough studies for adsorption of fluoride on activated alumina,” Separ. Purif. Technol., Vol. 42, No. 3, pp. 265-271.
Haribabu, E., Upadhya, Y.D. and Upadhyay, S.N., 1993, “Removal of phenols from effluents by fly ash,” Int. J. Environ. Studies, Vol. 43, No. 2/3, pp. 169-176.
Harrison, P.T.C., 2005, “Fluoride in water: a UK perspective,” J. Fluorine Chem., Vol. 126, No. 11/12, pp. 1448-1456.
Ho, Y.S. and McKay, G., 1999, “The sorption of lead (II) ions on peat”, Water Res., Vol. 33, No. 2, pp. 578-584.
Ho, Y.S., Ng, J.C.Y. and McKay, G., 2001, “Removal of lead (II) from effluents by sorption on peat using secondorder kinetics,” Sep. Sci. Technol., Vol. 36, No. 2, pp. 241-261.
Ho, Y.S. and Chiang, C.C., 2001, “Sorption studies of acid dye by mixed sorbents,” Adsorption, Vol. 7, No. 2, pp. 139-148.
Hsu, P.H., 1976, “Comparison of iron (III) and aluminum in precipitation of phosphate from solution,” Water Res., Vol. 10, No. 10, pp. 903-907.
Huang, C.J. and Liu, J.C., 1999, “Precipitate flotation of fluoride-containing wastewater from a semiconductor manufacturer,” Water Res., Vol. 33, No. 16, pp. 3403-3412.
Lagergren, S., 1898, “About the theory of so-called adsorption of soluble substances,” K. Svenska Vetenskapsakad Handl., Vol. 24, pp. 1-39.
Nordstrom, D.K., Ball, J.W., Donahoe, R.J. and Whittemore, D., 1989, “Groundwater chemistry and water-rock interaction at Stripa,” Geochimica et Cosmochimica Acta, Vol. 53, No. 8, pp. 1727-1740.
Panday, K.K., Prasad, G. and Singh, V.N., 1985, “Copper (II) removal from aqueous solutions by fly ash,” Water Res., Vol. 19, No. 7, pp. 869-873.
Periasamy, K. and Namasivayam, C., 1994, “Process development for removal and recovery of cadmium from wastewater by a low-cost adsorbent: Adsorption rates and equilibrium studies,” Ind. Eng. Chem. Res., Vol. 33, pp. 317-320.
Popat, K.M., Anand, P.S. and Dasare, B.D., 1994, “Selective removal of fluoride ions from water by the aluminium form of the aminomethylphosphonic acid-type ion exchanger,” React. Polym., Vol. 23, No. 1, pp. 23-32.
Reardon, E.J. and Wang, Y., 2000, “A limestone reactor for fluoride removal from wastewaters,” Environ. Sci. Technol., Vol. 34, No. 15, pp. 3247-3253.
Shen, F., Chen, X., Gao, P. and Chen, G., 2003, “Electrochemical removal of fluoride ions from industrial wastewater,” Chem. Eng. Sci., Vol. 58, No. 3/6, pp. 987-993.
Shanker, R., Thussu, J.L. and Prasad, J.M., 1987, “Geothermal studies at Tattapani hot spring area, Sarguja district, central India,” Geothermics, Vol. 16, No. 1, pp. 61-76.
Simons, R., 1993, “Trace element removal from ash dam waters by nanofiltration and diffusion dialysis,” Desalination, Vol. 89, No. 3, pp. 325-341.
Snoeyink, V.L., 1990, Adsorption of organic compounds. In: Pontius, F.W. (Ed.), Water Quality and Treatment. McGraw-Hill Inc., New York, pp. 781-876.
Steiner, M., Pronk, W. and Boller, M.A., 2006, “Modeling of copper sorption onto GFH and design of full-scale GFH adsorbers,” Environ. Sci. Technol., Vol. 40, No. 5, pp. 1629-1635.
Sujana, M.G., Thakur, R.S. and Rao, S.B., 1998, “Removal of fluoride from aqueous solution by using alum sludge,” J. Colloid Interf. Sci., Vol. 206, No. 1, pp. 94-101.
Teermann, I.P. and Jekel, M.R., 1999, “Adsorption of humic substances onto β-FeOOH and its chemical regeneration,” Water Sci. Technol., Vol. 40, No. 9, pp. 199-206.
Tutem, E., Apak, R. and Unal, C.F., 1998, “Adsorptive removal of chlorophenols from water by bituminous shale,” Water Res., Vol. 32, No. 8, pp. 2315-2324.
Weber Jr., W.J. and Morris, J.C., 1963, “Kinetics of adsorption on carbon from solution,” J. Sanit. Eng. Div., Vol. 89, pp. 31-59.
WHO, 2006, Chemical fact sheets: fluoride. In: Guidelines for drinking water quality (electronic resource): incorporation first addendum. Recommendations, Vol. 1, third ed., Geneva. pp. 375-377.

Information

Publisher :The Korean Society of Mineral and Energy Resources Engineers
Publisher(Ko) :한국자원공학회
Journal Title :Journal of the Korean Society for Geosystem Engineering
Journal Title(Ko) :한국지구시스템공학회지
Volume : 45
No :5
Pages :441-447

[1] 두산백과사전, 2008.

[2] 정기영, 김강주, 김종용, 박재형, 이도영, 박순길, 2003, “포항-경주지역 양산단층대 주변의 고불소 지하수 산출 특 성,” 지질학회지, 39권, 3호, pp. 371-384.

[3] 수자원환경, 1995, “불소의 정체를 밝힌다,” Vol. 79, pp.22-30.

[4] 환경부, 2006, 2006 하반기 민,관합동 수질검사결과.

[5] Adhikary, S.K., Tipnis, U.K., Harkare, W.P., and Govindan, K.P., 1989, “Defluoridation during desalination of brackish water by electrodialysis,” Desalination, Vol. 71, No. 3, pp. 301-312.

[6] Apambire, W.B., Boyle, D.R. and Michel, F.A., 1997, “Geochemistry, genesis, and health implications of fluoriferous groundwaters in the upper regions Ghana,” Environmental Geology, Vol. 33, No. 1, pp. 13-24.

[7] Banks, D., Reimann, C., Rǿyset, O., Skarphagen, H., and Saether, O.M., 1995, “Natural concentrations of major and trace elements in some Norwegian bedrock groundwaters,” Appl. Geochem, Vol. 10, No. 1, pp. 1-16.

[8] Benefield, L. D., Joseph, F., Judkins, JR, Barron L. Weand, 1982, “Process Chemistry for water and wastewater treatment,” Prentice-Hall, inc.

[9] Cox, G. J., 1939, “New knowledge of Fluorine in relation to dental caries,” J. Am. Water Works Assoc., Vol. 31, pp. 1926-1930.

[10] CDC (Centers for Disease Control and Prevention), 1999, Achievements in Public Health, 1900-1999: Fluoridization of drinking water to prevent dental caries. Morbidity and Mortality Weekly Report, 48, pp. 933-940.

[11] Dean, H.T., 1934, “Classification of mottled enamel diagnosis,” J. Am. Dent. Assoc., Vol. 12, pp. 1421-1426.

[12] Driehaus, W., 2002, “Arsenic removal - experience with the GEHⓇ process in Germany,” Water Supply, Vol. 2, No.2, pp. 275-280.

[13] Ghorai, S. and Pant, K.K., 2005, “Equilibrium, kinetics and breakthrough studies for adsorption of fluoride on activated alumina,” Separ. Purif. Technol., Vol. 42, No. 3, pp. 265-271.

[14] Haribabu, E., Upadhya, Y.D. and Upadhyay, S.N., 1993, “Removal of phenols from effluents by fly ash,” Int. J. Environ. Studies, Vol. 43, No. 2/3, pp. 169-176.

[15] Harrison, P.T.C., 2005, “Fluoride in water: a UK perspective,” J. Fluorine Chem., Vol. 126, No. 11/12, pp. 1448-1456.

[16] Ho, Y.S. and McKay, G., 1999, “The sorption of lead (II) ions on peat”, Water Res., Vol. 33, No. 2, pp. 578-584.

[17] Ho, Y.S., Ng, J.C.Y. and McKay, G., 2001, “Removal of lead (II) from effluents by sorption on peat using secondorder kinetics,” Sep. Sci. Technol., Vol. 36, No. 2, pp. 241-261.

[18] Ho, Y.S. and Chiang, C.C., 2001, “Sorption studies of acid dye by mixed sorbents,” Adsorption, Vol. 7, No. 2, pp. 139-148.

[19] Hsu, P.H., 1976, “Comparison of iron (III) and aluminum in precipitation of phosphate from solution,” Water Res., Vol. 10, No. 10, pp. 903-907.

[20] Huang, C.J. and Liu, J.C., 1999, “Precipitate flotation of fluoride-containing wastewater from a semiconductor manufacturer,” Water Res., Vol. 33, No. 16, pp. 3403-3412.

[21] Lagergren, S., 1898, “About the theory of so-called adsorption of soluble substances,” K. Svenska Vetenskapsakad Handl., Vol. 24, pp. 1-39.

[22] Nordstrom, D.K., Ball, J.W., Donahoe, R.J. and Whittemore, D., 1989, “Groundwater chemistry and water-rock interaction at Stripa,” Geochimica et Cosmochimica Acta, Vol. 53, No. 8, pp. 1727-1740.

[23] Panday, K.K., Prasad, G. and Singh, V.N., 1985, “Copper (II) removal from aqueous solutions by fly ash,” Water Res., Vol. 19, No. 7, pp. 869-873.

[24] Periasamy, K. and Namasivayam, C., 1994, “Process development for removal and recovery of cadmium from wastewater by a low-cost adsorbent: Adsorption rates and equilibrium studies,” Ind. Eng. Chem. Res., Vol. 33, pp. 317-320.

[25] Popat, K.M., Anand, P.S. and Dasare, B.D., 1994, “Selective removal of fluoride ions from water by the aluminium form of the aminomethylphosphonic acid-type ion exchanger,” React. Polym., Vol. 23, No. 1, pp. 23-32.

[26] Reardon, E.J. and Wang, Y., 2000, “A limestone reactor for fluoride removal from wastewaters,” Environ. Sci. Technol., Vol. 34, No. 15, pp. 3247-3253.

[27] Shen, F., Chen, X., Gao, P. and Chen, G., 2003, “Electrochemical removal of fluoride ions from industrial wastewater,” Chem. Eng. Sci., Vol. 58, No. 3/6, pp. 987-993.

[28] Shanker, R., Thussu, J.L. and Prasad, J.M., 1987, “Geothermal studies at Tattapani hot spring area, Sarguja district, central India,” Geothermics, Vol. 16, No. 1, pp. 61-76.

[29] Simons, R., 1993, “Trace element removal from ash dam waters by nanofiltration and diffusion dialysis,” Desalination, Vol. 89, No. 3, pp. 325-341.

[30] Snoeyink, V.L., 1990, Adsorption of organic compounds. In: Pontius, F.W. (Ed.), Water Quality and Treatment. McGraw-Hill Inc., New York, pp. 781-876.

[31] Steiner, M., Pronk, W. and Boller, M.A., 2006, “Modeling of copper sorption onto GFH and design of full-scale GFH adsorbers,” Environ. Sci. Technol., Vol. 40, No. 5, pp. 1629-1635.

[32] Sujana, M.G., Thakur, R.S. and Rao, S.B., 1998, “Removal of fluoride from aqueous solution by using alum sludge,” J. Colloid Interf. Sci., Vol. 206, No. 1, pp. 94-101.

[33] Teermann, I.P. and Jekel, M.R., 1999, “Adsorption of humic substances onto β-FeOOH and its chemical regeneration,” Water Sci. Technol., Vol. 40, No. 9, pp. 199-206.

[34] Tutem, E., Apak, R. and Unal, C.F., 1998, “Adsorptive removal of chlorophenols from water by bituminous shale,” Water Res., Vol. 32, No. 8, pp. 2315-2324.

[35] Weber Jr., W.J. and Morris, J.C., 1963, “Kinetics of adsorption on carbon from solution,” J. Sanit. Eng. Div., Vol. 89, pp. 31-59.

[36] WHO, 2006, Chemical fact sheets: fluoride. In: Guidelines for drinking water quality (electronic resource): incorporation first addendum. Recommendations, Vol. 1, third ed., Geneva. pp. 375-377.

Journal of the Korean Society of Mineral and Energy Resources Engineers ISSN:2288-0291(Print) 2288-2790(Online) 한국자원공학회지

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