Separation of Platinum from Platinum-scrap Leaching Model Solution(Pt, Rh, Al, Fe) Using Synthetic Extraction Resins

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2012 Vol.49, Issue 1 Preview Page Next Page

Research Paper

Separation of Platinum from Platinum-scrap Leaching Model Solution(Pt, Rh, Al, Fe) Using Synthetic Extraction Resins 합성 추출수지를 이용한 백금스크랩 침출모사액(Pt, Rh, Al, Fe) 으로부터 백금 분리: 한동혁·황인성·임광일·한 춘·이진영·김준수·박형규
Dong-Hyuk Han, In-Sung Hwang, Gwang-Il Lim, Choon Han, Jin-Young Lee, Joon-Soo Kim and Hyung-Kyu Park

29 February 2012. pp. 1-9

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Abstract

For the separation of Pt from platinum-scrap leaching model solutions(Pt, Rh, Al, Fe), extraction resins were synthesized and separation efficiencies were evaluated. During synthesis, the suspension polymerization method was adopted with D2EHPA and tri-butyl-phosphate(TBP) as extractants. Also, benzoyl peroxide as a starter was divided into 3 parts and injected for the uniform size and dispersion of resin particles. In case of synthetic resin with D2EHPA, almost all Fe and Al(99~100%) were extracted. Furthermore the synthetic resin with TBP extracted Pt selectively in Pt and Rh mixtures. Consequently, a small amount of synthetic resin(3~5wt%) was found enough for extractions of Fe and Al. In case of the synthetic resin with TBP, 5~10wt% of resin was enough for selective extraction of Pt(74%).

Keywords

Platinum

D2EHPA

Tri-butyl-phosphate

Synthetic resin

Suspension Polymerization method

백금스크랩 침출물(백금, 로듐, 알루미늄, 철)용액으로부터 백금 분리를 위하여, 추출제 D2EHPA와 tri-butyl-phosphate(TBP)를 이용하여 현탁중합법에 기초한 추출 수지를 합성하고 분리효율을 평가하였다. 수지합성 시 추출제의 고른 분산과 균일한 입자를 만들어 알루미늄과 철의 추출량을 증가시키고자 반응 개시제인 benzoyl peroxide(BPO)의 첨가법을 변화시켜 세 번 나누어 첨가하였다. D2EHPA를 이용하여 합성한 추출수지의 경우 백금 스크랩 침출물 내 Fe와 Al을 99~100% 추출하는 것을 확인하였다. 또한 침출물 내 잔류된 Pt와 Rh의 경우 TBP를 이용하여 합성한 추출수지가 Pt만 선택적으로 추출하는 것을 확인할 수 있었다. 두 수지 모두 55℃까지는 추출효율이 증가하나, 그 이상의 온도에서는 영향이 없는 것으로 확인되었으며, 추출수지의 첨가량에 따른 추출효율은 D2EHPA 수지의 경우 3~5%농도에서 최대 추출효율 99.5~99.9%를 확인하였고, TBP수지의 경우 5~10%농도에서 74%의 최대 추출효율을 확인하였다.

키워드

백금

D2EHPA

TBP

합성수지

현탁중합법

References

Bernadis., F.L., Grant., R.A. and Sherrington., F.C., 2005, “A review of methods of separation of the platinum-group metals though their chloro-complexes,” Reactive & functional polymers, Vol. 65, pp. 205-217.
Cui, J. and Zhang, L. 2008, “Metallurgical recovery of metals from electronic waste,” Journal of hazardous meterials, Vol. 158, pp. 228-256.
Shams, K. and Goodarzi, F., 2006, “Improved and selective platinum recovery from spent α-alumina supported catalysts using pretreated anionic ion exchange resin,” Journal of hazardous meterials, Vol. 131, pp. 229-237.
Kim, B.S., Lee, J.C. and Seo, S.P., 2003, “Development of a pyrometallurgical process for recovering precious metals simulataneously from used printed boards and auto catalysts,” Kor. J. Met, mater., Vol. 41, No. 6, pp. 377-382.
Lee, J.C., Jeong, J.K., Kim, M.S., Kim, B.S. and Kim, C.K., 2004, “Recovery of platinum group metals from spent automotive catalysts by hydrochloric acid leaching,” Journal of Korean Inst. of Resources Recycling, Vol. 13, No. 5, pp. 28-36.
Lokhande, T.N., Anuse, M.A. and Chavan, M.B., 1998, “Extraction and separate studies of platinum(IV) with N-n-octylaniline,” Talanta, Vol. 46, pp. 823-832.
David, J., 2009, Platinum 2009 interim review, Johnson Matthey Public Limited Company, England. pp. 3-36.
Christian, H., Matthias, B. and Peter, R., 2006, “Metals flow of platinum group metals in germany,” International Journal of Sustainable Manufacturing, Vol. 1, No. 3, pp. 330-346.
Schreier, G. and Edtmaier, C., 2003, “Separation of Ir, Pd and Rh from secondary Pt scrap by precipitation and calcination,” Hydrometallurgy, Vol. 68, pp. 69-75.
Nowottny, C., Halwachs, W. and Schügerl, K., 1997, “Recovery of platinum, palladium and rhodium from industrial process leaching solutions by reactive extraction,” Separation and purification technology, Vol.12, pp. 135-144.
Kim, J.H. and Lee, W.H., 1995, “Solvent extraction of platinum by tri-butyl-phosphate in HCl solution,” Kor. J. Met, mater, Vol. 33 No. 10, pp. 1382-1386.
Lee, M.S., Ahn, J.S. and Sun, P.P., 2010, “Effect of Cu(II) and Al(III) on the extraction and separation of Pt(IV) and Pd(II) from concentrated hydrochloric acid solution with Alamine336,” Kor. J. Met, mater, Vol. 48, No. 2, pp. 148-153.
Matsunaga, H., Ismail, A.A., Wakui, Y. and Yokoyama, T., 2001, “Extraction of rare earth elements with 2-ethylhexyl hydrogen 2-ethylhexyl phosphonate impregnated resins having different morphology and regent content”. Reactive and Functional Polymers, Vol. 49, pp. 189-195.
Kim, J.S., Han, C., Kim, J.H. and Kim, J.S., 2006, “Effect of polyvinyl alcohol on rare earths(Gd and Tb) separation by extraction resin,” Talanta, Vol. 68, pp. 963-968
Andreas, G., Walter, N. and Kim, J.I., 1999, “On the kinetics of rare-earth extraction into D2EHPA,” Chemical Engineering Science, Vol. 54, No. 12, pp. 1903-1907.
Jahanzad, F., Sajjadi, S. and Brooks, B.W., 2005, “Characteristic intervals in suspension polymerisation reactors: An experimental and modelling study,” Chemical Engineering Science, Vol.60, pp. 5574-5589.
Lim, G.I., Han, C., Han, D.H., Hwang, I.S., Lee, J.Y., Kim, J.S. and Park, H.K., 2011, “Separation of aluminum and iron from platinum mixture using synthetic extraction resins,” J. of Korean Inst. of Resources Recycling, Vol. 20, No. 3, pp. 68-76.
Han, C., Kim, J.S., Lee, J.Y., Park, K.M., Bae, J.S, and Park, J.W., 2008, “다성분계 희토류 원소의 추출분리를 위한 수지의 합성방법 (Synthesis Method of Extraction Resin for Separaton of Rare Earth Elements),” 출원번호 : 10-2008-0019512, 공개번호 : 10-2009-0094528.
Park, J.S., Han, C., Lee, J.Y., Kim, S.D., Kim, J.S. and Wee, J.H., 2005 “Synthesis of extraction resin containing 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester and its performance for separation of rare earths (Gd, Tb),” Separation and Purification Technology, Vol. 43, No. 2, pp. 111-116.
Park, J.S., Cho, J.W., Kim, D.H. and Han, C., 2004, “Synthesis of Extraction Resin Containing Bis(2-Ethylhexyl) phosphnic Acid and Seperation of Heavy Rare Earth Elements(Gd, Tb),” J. of The Korean Society for Geosystem Engineering, Vol. 41, No. 1, pp. 69-76
Park, S.K., Bae, J.S., Hwang, I.S., Lee, J.Y., Yoon, H.S., Kim, J.S. and Han, C., 2011, “Adsorption/Desorption Behavior of Uranium by Synthetic Ion Exchange Resin using Tetramethylammonium Hydroxide Pentahydrate ((CH3)4NOH·5H2O),” J. of The Korean Society for Geosystem Engineering, Vol. 48, No. 4.
Richard, I.M., 1996, principles of adsorption and reaction and on solid surfaces, pp. 507-514.
Richard, I.M., 2001, chemical kinetics and catalysis, Wiley-Interscience, 1st Ed., pp. 30-35.

Information

Publisher :The Korean Society of Mineral and Energy Resources Engineers
Publisher(Ko) :한국자원공학회
Journal Title :Journal of the Korean Society for Geosystem Engineering
Journal Title(Ko) :한국지구시스템공학회지
Volume : 49
No :1
Pages :1-9

[1] Bernadis., F.L., Grant., R.A. and Sherrington., F.C., 2005, “A review of methods of separation of the platinum-group metals though their chloro-complexes,” Reactive & functional polymers, Vol. 65, pp. 205-217.

[2] Cui, J. and Zhang, L. 2008, “Metallurgical recovery of metals from electronic waste,” Journal of hazardous meterials, Vol. 158, pp. 228-256.

[3] Shams, K. and Goodarzi, F., 2006, “Improved and selective platinum recovery from spent α-alumina supported catalysts using pretreated anionic ion exchange resin,” Journal of hazardous meterials, Vol. 131, pp. 229-237.

[4] Kim, B.S., Lee, J.C. and Seo, S.P., 2003, “Development of a pyrometallurgical process for recovering precious metals simulataneously from used printed boards and auto catalysts,” Kor. J. Met, mater., Vol. 41, No. 6, pp. 377-382.

[5] Lee, J.C., Jeong, J.K., Kim, M.S., Kim, B.S. and Kim, C.K., 2004, “Recovery of platinum group metals from spent automotive catalysts by hydrochloric acid leaching,” Journal of Korean Inst. of Resources Recycling, Vol. 13, No. 5, pp. 28-36.

[6] Lokhande, T.N., Anuse, M.A. and Chavan, M.B., 1998, “Extraction and separate studies of platinum(IV) with N-n-octylaniline,” Talanta, Vol. 46, pp. 823-832.

[7] David, J., 2009, Platinum 2009 interim review, Johnson Matthey Public Limited Company, England. pp. 3-36.

[8] Christian, H., Matthias, B. and Peter, R., 2006, “Metals flow of platinum group metals in germany,” International Journal of Sustainable Manufacturing, Vol. 1, No. 3, pp. 330-346.

[9] Schreier, G. and Edtmaier, C., 2003, “Separation of Ir, Pd and Rh from secondary Pt scrap by precipitation and calcination,” Hydrometallurgy, Vol. 68, pp. 69-75.

[10] Nowottny, C., Halwachs, W. and Schügerl, K., 1997, “Recovery of platinum, palladium and rhodium from industrial process leaching solutions by reactive extraction,” Separation and purification technology, Vol.12, pp. 135-144.

[11] Kim, J.H. and Lee, W.H., 1995, “Solvent extraction of platinum by tri-butyl-phosphate in HCl solution,” Kor. J. Met, mater, Vol. 33 No. 10, pp. 1382-1386.

[12] Lee, M.S., Ahn, J.S. and Sun, P.P., 2010, “Effect of Cu(II) and Al(III) on the extraction and separation of Pt(IV) and Pd(II) from concentrated hydrochloric acid solution with Alamine336,” Kor. J. Met, mater, Vol. 48, No. 2, pp. 148-153.

[13] Matsunaga, H., Ismail, A.A., Wakui, Y. and Yokoyama, T., 2001, “Extraction of rare earth elements with 2-ethylhexyl hydrogen 2-ethylhexyl phosphonate impregnated resins having different morphology and regent content”. Reactive and Functional Polymers, Vol. 49, pp. 189-195.

[14] Kim, J.S., Han, C., Kim, J.H. and Kim, J.S., 2006, “Effect of polyvinyl alcohol on rare earths(Gd and Tb) separation by extraction resin,” Talanta, Vol. 68, pp. 963-968

[15] Andreas, G., Walter, N. and Kim, J.I., 1999, “On the kinetics of rare-earth extraction into D2EHPA,” Chemical Engineering Science, Vol. 54, No. 12, pp. 1903-1907.

[16] Jahanzad, F., Sajjadi, S. and Brooks, B.W., 2005, “Characteristic intervals in suspension polymerisation reactors: An experimental and modelling study,” Chemical Engineering Science, Vol.60, pp. 5574-5589.

[17] Lim, G.I., Han, C., Han, D.H., Hwang, I.S., Lee, J.Y., Kim, J.S. and Park, H.K., 2011, “Separation of aluminum and iron from platinum mixture using synthetic extraction resins,” J. of Korean Inst. of Resources Recycling, Vol. 20, No. 3, pp. 68-76.

[18] Han, C., Kim, J.S., Lee, J.Y., Park, K.M., Bae, J.S, and Park, J.W., 2008, “다성분계 희토류 원소의 추출분리를 위한 수지의 합성방법 (Synthesis Method of Extraction Resin for Separaton of Rare Earth Elements),” 출원번호 : 10-2008-0019512, 공개번호 : 10-2009-0094528.

[19] Park, J.S., Han, C., Lee, J.Y., Kim, S.D., Kim, J.S. and Wee, J.H., 2005 “Synthesis of extraction resin containing 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester and its performance for separation of rare earths (Gd, Tb),” Separation and Purification Technology, Vol. 43, No. 2, pp. 111-116.

[20] Park, J.S., Cho, J.W., Kim, D.H. and Han, C., 2004, “Synthesis of Extraction Resin Containing Bis(2-Ethylhexyl) phosphnic Acid and Seperation of Heavy Rare Earth Elements(Gd, Tb),” J. of The Korean Society for Geosystem Engineering, Vol. 41, No. 1, pp. 69-76

[21] Park, S.K., Bae, J.S., Hwang, I.S., Lee, J.Y., Yoon, H.S., Kim, J.S. and Han, C., 2011, “Adsorption/Desorption Behavior of Uranium by Synthetic Ion Exchange Resin using Tetramethylammonium Hydroxide Pentahydrate ((CH3)4NOH·5H2O),” J. of The Korean Society for Geosystem Engineering, Vol. 48, No. 4.

[22] Richard, I.M., 1996, principles of adsorption and reaction and on solid surfaces, pp. 507-514.

[23] Richard, I.M., 2001, chemical kinetics and catalysis, Wiley-Interscience, 1st Ed., pp. 30-35.

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